More than likely he did not have them put in. The only way to tell is to take the heads off the engine, remove the valves and look at the valve seats. If he had them replaced they would have had to be pressed in and then machined so as to seat the valves. You would see a distinctly different color between the head and the seats.
Depending on how many miles are on the engine its hard to say if/how much damage would have been done to the valve seats. There is more than likely a bit if the engine was run over a long period of time with unleaded fuel. I would not be too concerned about it as long as the engine runs well. You could do a compression test to check and see that all the cylinders have nearly the same pressure. If some are way off it is possible the seats have sunk and your valve to seat seal has been compromised.
Since you are running 110 leaded you won't have any more concerns about valve seat wear but if you want to save some money on fuel go to
http://www.maxlead2000.com/ and check out a product called Max Lead 2000. You can add this to your fuel and it will protect your valve seats because it is real tetraethyl lead which was added to the fuel of yesteryear. I used to run it in mine until I got my timing figured out, even though I have the hardened valve seats. Tetraethyl lead also stabilizes your fuel and bumps up the octane to prevent pinging and detonation (which was my problem due to my domed pistons resulting in higher than stock compression). It works very well. I experimented with the amount to add, finally settling on 200 ml per tankful (about 6 oz.) Check out the website to get the lowdown on it.
It may be $45 per gallon but at 8 oz. per tankful it will last you 16 tankfuls. If you only need 6 oz. per tankful then it will last 21.33 tankfuls. At 10 mpg you'll have enough to go 3200-4266 miles or about 1 year's worth of driving if you only drive the car now and then. Doing the math, 8 oz. of Max. Lead 2000 will add $2.81 to the cost of a tank of gas while 6 oz. will add $2.11. If you are concerned about valve seat recession or are having problems with pinging, run-on, or detonation then this may be the answer you've been looking for.